DFT Analysis of Vanadium Tris(Dithiolene)-Based Double-Gated Single-Electron Transistor
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Electronic Materials"
DOI: 10.1007/s11664-020-08132-8
Abstract: A double-gated single-electron transistor (SET) based on metal–organic complex vanadium tris(dithiolene) has been modelled and investigated for the operation and electrostatics analysis. Density functional theory and non-equilibrium Green’s function method have been opted for first-principle… read more here.
Keywords: double gated; single electron; gated single; vanadium tris ... See more keywords
Electronic versatility of vanadium in tris-chelates with redox-active ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00672c
Abstract: Spectroscopic and computational examination of the neutral tris-dioxolene complex [V(dbcat)3] (dbcat2- = 3,6-di-tert-butylcatecholate) reveals a Class III mixed-valent ground state. The radical is stabilised by delocalisation across the ligands mediated by the energy matched d… read more here.
Keywords: tris chelates; redox active; vanadium tris; electronic versatility ... See more keywords