Stereospecific synthesis of S-(-)-trans-verbenol and its antipode by inversion of sterically hindered alcohols.
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DOI: 10.1080/10286020.2020.1839433
Abstract: S-(-)-trans-Verbenol (1) and its antipode, R-(+)-trans-verbenol (1') have been confirmed as the critical pheromone components of bark beetles. Synthesis of these two active secondary alcohols (1 and 1') from commercially available starting materials S-α-pinene and… read more here.
Keywords: hindered alcohols; inversion; stereospecific synthesis; sterically hindered ... See more keywords