Detection and Verification of a Key Intermediate in an Enantioselective Peptide Catalyzed Acylation Reaction
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DOI: 10.3390/molecules27196351
Abstract: Until now, the intermediate responsible for the acyl transfer of a highly enantioselective tetrapeptide organocatalyst for the kinetic resolution of trans-cycloalkane-1,2-diols has never been directly observed. It was proposed computationally that a π-methylhistidine moiety is… read more here.
Keywords: verification key; reaction; spectroscopy; acylation ... See more keywords