Activated Glycerol Carbonates, Versatile Reagents with Aliphatic Amines: Formation and Reactivity of Glycidyl Carbamates and Trialkylamines
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Organic Chemistry"
DOI: 10.1002/ejoc.201700646
Abstract: The reactivity of mesylated and tosylated glycerol carbonate towards secondary and tertiary amines has been studied, and allowed regioselective access to carbamates which could then be transformed into glycidylcarbamates. By tuning the reaction conditions, we… read more here.
Keywords: activated glycerol; glycerol carbonates; glycerol; reactivity ... See more keywords
Bicyclobutanes: from curiosities to versatile reagents and covalent warheads
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d2sc03948f
Abstract: The unique chemistry of small, strained carbocyclic systems has long captivated organic chemists from a theoretical and fundamental standpoint. A resurgence of interest in strained carbocyclic species has been prompted by their potential as bioisosteres,… read more here.
Keywords: bicyclobutanes curiosities; versatile reagents; chemistry; covalent warheads ... See more keywords
Disulfides turned out to be versatile S-reagents: effective sulfonylation of alkenes with disulfides under electrochemical conditions
Sign Up to like & getrecommendations! Published in 2023 at "Organic Chemistry Frontiers"
DOI: 10.1039/d3qo00589e
Abstract: Electrochemically induced sulfonylation of alkenes with disulfides as the starting reagents was developed. This transformation is a quite rare example of disulfides usage as S-partners in electrochemical C-S coupling. In... read more here.
Keywords: turned versatile; versatile reagents; sulfonylation alkenes; disulfides turned ... See more keywords