Electronic versatility of vanadium in tris-chelates with redox-active ligands.
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DOI: 10.1039/d2dt00672c
Abstract: Spectroscopic and computational examination of the neutral tris-dioxolene complex [V(dbcat)3] (dbcat2- = 3,6-di-tert-butylcatecholate) reveals a Class III mixed-valent ground state. The radical is stabilised by delocalisation across the ligands mediated by the energy matched d… read more here.
Keywords: tris chelates; redox active; vanadium tris; electronic versatility ... See more keywords