Trimethylsilyl versus Bis(trimethylsilyl) Substitution in Tris(cyclopentadienyl) Complexes of La, Ce, and Pr: Comparison of Structure, Magnetic Properties, and Reactivity
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DOI: 10.1021/acs.organomet.7b00881
Abstract: To evaluate the effect of cyclopentadienyl ligand substitution in complexes of new +2 ions of the lanthanides, comparisons in reactivity and spectroscopic and magnetic properties have been made between [K(crypt)][Cp′3Ln], 1-Ln (Cp′ = C5H4SiMe3; crypt… read more here.
Keywords: trimethylsilyl versus; cyclopentadienyl; magnetic properties; reactivity ... See more keywords