Mono Versus Dinuclear Vanadium(V) Complexes: Solvent Dependent Structural Versatility and Electro Syntheses of Mixed-Valence Oxovanadium(IV/V) Entities in Solution
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.1c06713
Abstract: Two mononuclear oxidovanadium(V) complexes type of [VVO(L1)(OMe)(MeOH)] (1), [VVO(L2)(OMe)(MeOH)] (2) and two [V2O3]4+ core of μ-oxidodioxidodivanadium(V) complexes (L1)(O)VV–O–VV(O)(L1) (3) and (L2)(O)VV–O–VV(O)(L2) (4) and two complexes [VVO(L1)(8-Hq)] (5) and [VVO(L2)(8-Hq)] (6) incorporating 8-hydroxyquinoline (8-hq) as co-ligand… read more here.
Keywords: vanadium; versus dinuclear; geometry; mixed valence ... See more keywords
Synthesis and SMM behaviour of trinuclear versus dinuclear 3d-5f uranyl(v)-cobalt(ii) cation-cation complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c6dt04558h
Abstract: Trinuclear versus dinuclear heterodimetallic UVO2+Co2+ complexes were selectively assembled via a cation-cation interaction by tuning the ligand. The trimeric complex 2, with a linear [Co-O[double bond, length as m-dash]U[double bond, length as m-dash]O-Co] core, exhibits… read more here.
Keywords: cation; synthesis smm; versus dinuclear; trinuclear versus ... See more keywords