Fe SAC on Nitrogen‐Doped Carbon: An Efficient Catalyst for S‐Alkylation of Dithiocarbamates via Borrowing Hydrogen Strategy
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DOI: 10.1002/ajoc.202400032
Abstract: Herein we report, the synthesis of single‐atom iron on nitrogen‐doped carbon as a catalyst for the direct formation of Csp3‐S bond via borrowing hydrogen strategy using alcohols as the alkylating agent. The catalyst was synthesized… read more here.
Keywords: borrowing hydrogen; catalyst; nitrogen doped; doped carbon ... See more keywords
Divergent reactions of oxindoles with amino alcohols via the borrowing hydrogen process: oxindole ring opening vs. C3 alkylation
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DOI: 10.1039/c8qo00184g
Abstract: Oxindoles display a diverse pattern of reactivity upon reaction with different classes of amino alcohols via the borrowing hydrogen process. Whereas the reaction with N-acetyl amino alcohols leads to C3 alkylation, the reaction with N-alkyl… read more here.
Keywords: via borrowing; borrowing hydrogen; amino alcohols; reaction ... See more keywords
Ruthenium-catalysed N-alkylation of anilines with primary carbohydrate alcohols via borrowing hydrogen strategy.
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DOI: 10.1039/d3cc01931d
Abstract: Ruthenium-catalysed N-alkylation of anilines with sugar derivatives proceeded via the borrowing hydrogen strategy. Primary carbohydrate alcohols were successfully applied to N-alkylation of aniline derivatives to give the corresponding aminosugars in high yields. read more here.
Keywords: via borrowing; alkylation anilines; alkylation; borrowing hydrogen ... See more keywords
CrCl2-Catalyzed α-Alkylation of Carbonyl Compounds via Borrowing Hydrogen Approach
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DOI: 10.1039/d3qo01862h
Abstract: A new and efficient catalytic system for sustainable α-alkylation of carbonyl compounds with alcohols which serve as alkylating agents via a borrowing hydrogen strategy was presented. The developed practical catalytic... read more here.
Keywords: carbonyl compounds; borrowing hydrogen; alkylation carbonyl; via borrowing ... See more keywords
Ru-Catalyzed Domino C-4 Alkylation and Hydroxylation of Pyrazolones Using Alcohols via Borrowing-Hydrogen Catalysis
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DOI: 10.1055/a-2709-7683
Abstract: Herein, we developed a domino approach for the C-4-functionalization of pyrazolones, which includes sequential C-4 alkylation and C–H hydroxylation with alcohols to achieve C-4-substituted pyrazolones and pyrazoles via borrowing-hydrogen catalysis. The method is successfully facilitated… read more here.
Keywords: borrowing hydrogen; domino; alkylation hydroxylation; via borrowing ... See more keywords