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Published in 2024 at "ACS macro letters"
DOI: 10.1021/acsmacrolett.4c00703
Abstract: Poly(arylene ether)s (PAEs) are a versatile class of thermoplastic materials with commercial importance. Currently their synthesis relies predominantly on either nucleophilic or electrophilic aromatic substitution reactions, severely limiting the scope of available PAEs. Herein, we…
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Keywords:
poly arylene;
paes;
via catalysis;
ether via ... See more keywords
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Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c08130
Abstract: Transition-metal-catalyzed amination of aryl halides is one of the most employed methods for constructing N-arylation adducts. However, the broad success of these reactions largely relies on the screening of precatalysts, elaborated ligands, and case-by-case optimization…
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Keywords:
via catalysis;
photochemical amination;
amination;
amination via ... See more keywords