Formation of Alkynylgermyl-Substituted Germylenes via a Catenation of Ge Atoms.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c01244
Abstract: Reactions of amidinate-stabilized germylene chlorides R1Ge(:)Cl (R1 = PhC(NtBu)2) and R2Ge(:)Cl (R2 = PhC(NCy)2, Cy = cyclohexanyl) with trimethylsilylethynyl lithium salt (LLi, L = -C≡CTMS) afforded alkynylgermyl-substituted germylenes R1(:)Ge-GeL3 (1) and [R2GeL2]2Ge(:) (2), respectively. Both… read more here.
Keywords: via catenation; formation alkynylgermyl; germylenes via; alkynylgermyl substituted ... See more keywords
Unusual porous crystals via catenation of 1D ladders: unprecedented mixture effects on the adsorption of xylene isomers in a SCSC mode
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DOI: 10.1039/d0ce01458c
Abstract: Self-assembly of silver(I) perchlorate with a C3-symmetric tridentate N-donor ligand produces stable crystals with open channels via catenation of 1D ladder-type coordination polymers. The open-channel crystal shows both unprecedented mixture and temperature effects on the… read more here.
Keywords: via catenation; porous crystals; unprecedented mixture; scsc mode ... See more keywords