Iron-Catalyzed Borylation of Aryl Ethers via Cleavage of C-O Bonds.
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DOI: 10.1021/acs.orglett.0c00679
Abstract: Herein, we report the iron-catalyzed borylation of aryl ethers and aryl amines via cleavage of C-O and C-N bonds. This protocol does not require the use of Grignard reagents and displays a broad substrate scope,… read more here.
Keywords: aryl ethers; catalyzed borylation; borylation; via cleavage ... See more keywords
[2+2+2] Annulation of N-(1-Naphthyl)acetamide with Two Alkynoates via Cleavage of Adjacent C–H and C–N Bonds Catalyzed by an Electron-Deficient Rhodium(III) Complex
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DOI: 10.3390/molecules23123325
Abstract: It has been established that an electron-deficient cationic CpE-rhodium(III) complex catalyzes the non-oxidative [2+2+2] annulation of N-(1-naphthyl)acetamide with two alkynoates via cleavage of the adjacent C–H and C–N bonds to give densely substituted phenanthrenes under… read more here.
Keywords: annulation; naphthyl acetamide; cleavage; via cleavage ... See more keywords