Precise Control of Radial Catenane Synthesis via Clipping and Pumping.
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DOI: 10.1021/jacs.1c12303
Abstract: An unprecedented molecular pumping cassette was designed and implemented for the construction of molecular necklaces, that is, radial [n]catenanes. The mechanism was fully confirmed on a model [2]pseudorotaxane, and the novel clipping-followed-by-pumping strategy was used… read more here.
Keywords: via clipping; radial catenane; precise control; catenane synthesis ... See more keywords