Diastereoselective Synthesis of Boryl-Substituted Vinylcyclopropanes via Deborylative Cyclization of Geminal Diboron Compounds.
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DOI: 10.1021/acs.orglett.5c00886
Abstract: Herein we report a diastereoselective synthesis of boryl-substituted vinylcyclopropanes, a class of highly valuable synthetic building blocks, via deborylative cyclization of geminal diboron compounds. The method exhibits broad functional group tolerance and accommodates diverse alkyl… read more here.
Keywords: boryl substituted; substituted vinylcyclopropanes; diastereoselective synthesis; via deborylative ... See more keywords