Pd-Catalyzed Asymmetric Dearomative Arylation of Indoles via a Desymmetrization Strategy.
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DOI: 10.1021/acs.orglett.2c00129
Abstract: Pd-catalyzed asymmetric dearomative arylation of C3-substituted indoles is realized via a desymmetrization strategy. A BINOL-derived chiral phosphoramidite ligand is found to be highly efficient for the stereoselective control in this reaction. This method provides a… read more here.
Keywords: dearomative arylation; catalyzed asymmetric; desymmetrization strategy; via desymmetrization ... See more keywords
Synthetic Study on Carthamin. 2. Stereoselective Approach to C-Glycosyl Quinochalcone via Desymmetrization.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.6b03899
Abstract: Toward the total synthesis of carthamin, a stereoselective approach to the C-glycosyl quinochalcone intermediate is reported via the desymmetrization of a pseudo-Cs-symmetric C-glycosyl cyclohexadienone. read more here.
Keywords: carthamin stereoselective; approach glycosyl; glycosyl; glycosyl quinochalcone ... See more keywords