Cu(II)-Catalyzed, Site Selective Sulfoximination to Indole and Indolines via Dual C-H/N-H Activation.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c02817
Abstract: A copper-catalyzed protocol furnishing N-arylated sulfoximines has been developed via dual N-H/C-H activation. Arylalkyl- and less reactive diarylsulfoximines were efficiently coupled with privileged scaffolds like indolines, indoles, and N-Ar-7-azaindoles. Sulfoximines based on medicinally relevant scaffolds… read more here.
Keywords: selective sulfoximination; dual activation; site selective; catalyzed site ... See more keywords
Rhodium(III)-Catalyzed Oxidative Annulation of 2,2'-Bipyridine N-Oxides with Alkynes via Dual C-H Bond Activation.
Sign Up to like & getrecommendations! Published in 2018 at "Organic letters"
DOI: 10.1021/acs.orglett.8b01434
Abstract: Rh(III)-catalyzed switchable annulation of 2,2'-bipyridine N-oxides with internal alkynes via dual C-H bond activation has been developed. Tuning the reaction conditions enabled the reaction pathway to be switched between rollover and nonrollover annulation, delivering 5,6-disubstituted-1,10-phenanthrolines… read more here.
Keywords: annulation bipyridine; annulation; via dual; bipyridine oxides ... See more keywords
N-Arylation of NH-Sulfoximines via Dual Nickel Photocatalysis
Sign Up to like & getrecommendations! Published in 2019 at "Organic Letters"
DOI: 10.1021/acs.orglett.9b00698
Abstract: The pharmaceutically underexplored sulfoximine moiety has emerged as a potentially active pharmaceutical ingredient. We developed a scalable synthetic route to N-arylated sulfoximines from the respective “free” NH-sulfoximines and bromoarenes. Our strategy is based on a… read more here.
Keywords: via dual; arylation sulfoximines; dual nickel; nickel photocatalysis ... See more keywords
Octahedral Distortion Co-Regulation via Dual Strategies toward Luminescence Enhancement for the MA4InBr7 Perovskite Single Crystal.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.2c17964
Abstract: A series of novel perovskite single crystals are innovatively grown. Aiming to enhance the luminescence performance, octahedral distortion co-regulation via dual strategies for the as-prepared perovskite single crystals is performed. The distortion of the octahedral… read more here.
Keywords: octahedral distortion; perovskite single; regulation via; dual strategies ... See more keywords
Boosting Superconducting Properties of Fe(Se, Te) via Dual-Oscillation Phenomena Induced by Fluorine Doping.
Sign Up to like & getrecommendations! Published in 2019 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b02469
Abstract: Fluorine-doped Fe(Se, Te) has been successfully synthesized using the melting method. A dual-oscillation effect was found in the F-doped sample, which combined both microstructural oscillation and chemical compositional oscillation. The microstructural oscillation could be attributed… read more here.
Keywords: via dual; superconducting properties; oscillation; properties via ... See more keywords