Diverse Alkyl-Silyl Cross-Coupling via Homolysis of Unactivated C(sp3)-O Bonds with the Cooperation of Gold Nanoparticles and Amphoteric Zirconium Oxides.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12311
Abstract: Since C(sp3)-O bonds are a ubiquitous chemical motif in both natural and artificial organic molecules, the universal transformation of C(sp3)-O bonds will be a key technology for achieving carbon neutrality. We report herein that gold… read more here.
Keywords: sp3 bonds; gold nanoparticles; gold; via homolysis ... See more keywords
C-H bond activations by the HO˙/(Salophent-Bu)Co(II) radical pair generated via homolysis of a terminal Co(III)-OH bond.
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DOI: 10.1039/d3cc00146f
Abstract: The reactive HO˙/(Salophent-Bu)Co(II) radical pair was observed to be generated via homolysis of the terminal Co(III)-OH bond in transient (Salophent-Bu)(L)Co(III)(OH) (L = Py, MeOH) complexes as indicated by UV-Vis and EPR measurements. Based on this… read more here.
Keywords: radical pair; iii; generated via; salophent radical ... See more keywords