Articles with "via homolytic" as a keyword



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NHC induced radical formation via homolytic cleavage of B–B bonds and its role in organic reactions

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Published in 2022 at "Chemical Science"

DOI: 10.1039/d2sc02096c

Abstract: New borylation methodologies have been reported recently, wherein diboron(4) compounds apparently participate in free radical couplings via the homolytic cleavage of the B–B bond. We report herein that bis-NHC adducts of the type (NHC)2·B2(OR)4, which… read more here.

Keywords: cleavage; aryl iodides; homolytic cleavage; formation ... See more keywords