Transformation of Thioester-Initiated Star Polymers into Linear Arms via Native Chemical Ligation.
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DOI: 10.1002/marc.201900247
Abstract: The synthesis of a new class of Cu-mediated polymerization initiators with thioester functionality is demonstrated and their polymerization kinetics via single-electron transfer living radical polymerization is reported. From periodic sampling, it is found that thioester-… read more here.
Keywords: native chemical; linear arms; chemical ligation; via native ... See more keywords