Transition-Metal-Free Homopolymerization of Pyrrolo[2,3-d:5,4-d']bisthiazoles via Nucleophilic Aromatic Substitution.
Sign Up to like & getrecommendations! Published in 2021 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c10858
Abstract: Novel methods to synthesize electron-deficient π-conjugated polymers utilizing transition-metal-free coupling reactions for the use of nonfunctionalized monomers are attractive due to their improved atom economy and environmental prospective. Herein we describe the use of iPrMgCl·LiCl… read more here.
Keywords: via nucleophilic; transition; transition metal; nucleophilic aromatic ... See more keywords
Postfunctionalization of a Perfluoroarene-Containing π-Conjugated Polymer via Nucleophilic Aromatic Substitution Reaction
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DOI: 10.1021/acsmacrolett.9b01020
Abstract: Postfunctionalization is a useful strategy to tune the properties of conjugated polymers, while polymer reactions in the main chain of a conjugated backbone are still underexplored. Here we report ... read more here.
Keywords: via nucleophilic; containing conjugated; postfunctionalization perfluoroarene; perfluoroarene containing ... See more keywords
Synthesis of 2,4-Disubstituted Imidazoles via Nucleophilic Catalysis
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DOI: 10.1055/s-0039-1690832
Abstract: A convergent, microwave-assisted protocol for the synthesis of disubstituted NH-imidazoles via nucleophilic catalysis is described. The substituted imidazoles are accessed via the intramolecular addition of a variety of amidoxime substrates to activated alkynes followed by… read more here.
Keywords: via nucleophilic; nucleophilic catalysis; disubstituted imidazoles; synthesis disubstituted ... See more keywords