Indole Alkaloid Synthesis via Radical Cascade Reactions
Sign Up to like & getrecommendations! Published in 2017 at "Chem"
DOI: 10.1016/j.chempr.2017.05.012
Abstract: Mr. Xiaobei Wang is currently a fifth-year PhD student within Prof. Yong Qin's research group at Sichuan University. He was born in Anhui Province and obtained his BSc degree in pharmacy from Sichuan University in… read more here.
Keywords: synthesis; alkaloid synthesis; via radical; sichuan university ... See more keywords
Synthesis of α,α-difluorobenzoyl oxygen heterocycles via the radical reaction of 2-iodo-2,2-difluoroacetophenones with unsaturated acids or unsaturated alcohols
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2017.06.003
Abstract: Abstract A convenient and facile method for the direct synthesis of α,α-difluorobenzoyl lactones or cyclic ethers via the radical cyclization reaction of 2-iodo-2,2-difluoroacetophenone with unsaturated acids or alcohols was reported. read more here.
Keywords: unsaturated acids; reaction iodo; synthesis difluorobenzoyl; via radical ... See more keywords
A Visible-Light Organophotoredox-Catalyzed anti-Markovnikov Hydrocarbamoylation of Unactivated Alkene and Cyclization Cascade via Radical Relay.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c02878
Abstract: An organophotoredox-catalyzed anti-Markovnikov addition of the carbamoyl radical generated through the homolytic cleavage of 4-carbamoyl-1,4-dihydropyridine to the challenging unactivated alkene has been developed. Interestingly, the amino acid-derived carbamoyl precursor provided a unique opportunity for N-terminus… read more here.
Keywords: anti markovnikov; catalyzed anti; organophotoredox catalyzed; radical relay ... See more keywords
Introduction of Periodic Ketone Units on Vinyl Polymers via a Radical Alternating Copolymerization and Postpolymerization Modification: Sequence-Oriented Photodegradation in the Bulk State
Sign Up to like & getrecommendations! Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c13090
Abstract: The synthesis and the sequence-oriented bulk-state photodegradation of sequence-controlled polymers with a periodic structure bearing acrylamide, ketone, and vinyl ether units is reported. The alternating terpolymers can be synthesized via a radical copolymerization of a… read more here.
Keywords: sequence oriented; sequence; bulk state; photodegradation ... See more keywords
Construction methodologies and sequence-oriented properties of sequence-controlled oligomers/polymers generated via radical polymerization
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Journal"
DOI: 10.1038/s41428-020-00405-7
Abstract: The chain-growth polymerization mechanism is essentially unsuitable for sequence control due to the statistical propagation feature. However, the development of reversible-deactivation radical polymerization (RDRP) has opened the door to sequence control for carbon–carbon bond-based synthetic… read more here.
Keywords: polymerization; radical polymerization; sequence controlled; controlled oligomers ... See more keywords
Visible light-induced aryltrifluoromethylation of hydroxy alkenes via radical trifluoromethylation-triggered aryl and heteroaryl migration
Sign Up to like & getrecommendations! Published in 2018 at "Organic chemistry frontiers"
DOI: 10.1039/c8qo00430g
Abstract: An efficient protocol was developed to achieve the aryltrifluoroalkylation of hydroxy alkenes via radical trifluoromethylation-triggered aryl migration. This method possesses several interesting features: (I) visible light is used as the sole promoter; (II) a new… read more here.
Keywords: hydroxy alkenes; alkenes via; radical trifluoromethylation; migration ... See more keywords
Structure-Property Correlation of Hydrogels Obtained via Radical Polymerization Using Central Cores of Multiarm Star Polymers as Crosslinkers
Sign Up to like & getrecommendations! Published in 2025 at "Polymer Chemistry"
DOI: 10.1039/d5py00014a
Abstract: To improve mechanical properties of a hydrogel, the construction of uniform network structures and/or the incorporation of energy-dissipating structures are important. In this study, we focused on gel synthesis using... read more here.
Keywords: hydrogels obtained; property correlation; correlation hydrogels; obtained via ... See more keywords
Sustainable Electrically Conductive Bio-Based Composites via Radical-Induced Cationic Frontal Photopolymerization
Sign Up to like & getrecommendations! Published in 2024 at "Polymers"
DOI: 10.3390/polym16152159
Abstract: Diglycidylether of vanillyl alcohol (DGEVA), in combination with mechanically recycled carbon fibers (RCFs), was used to make, via Radical-Induced Cationic Frontal Photopolymerization (RICFP), fully sustainable and bio-based conductive composites with good electrical conductivity and consequent… read more here.
Keywords: radical induced; cationic frontal; frontal photopolymerization; induced cationic ... See more keywords