SYNTHESIS OF 2-POLYFLUOROALKYL-2,3-DIHYDRO-1,3,4-THIADIAZOLES VIA REGIOSELECTIVE [3+2] CYCLOADDITION OF NITRILE IMINES TO POLYFLUOROALKANETHIOAMIDES
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/4095
Abstract: Исследованы реакции [3+2]-циклоприсоединения амидов полифторалкантиокарбоновых кислот с нитрилиминами, генерированными in situ путем дегидрохлорирования соответствующих гидразоноилхлоридов при действии триэтиламина. На основе этих реакций предложен новый метод синтеза 2-полифторалкил-2,3-дигидро-1,3,4-тиадиазолов. read more here.
Keywords: dihydro thiadiazoles; polyfluoroalkyl dihydro; thiadiazoles via; synthesis polyfluoroalkyl ... See more keywords
Uncanonical Semireduction of Quinolines and Isoquinolines via Regioselective HAT-Promoted Hydrosilylation.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c11664
Abstract: Heterocycles are the backbone of modern medical chemistry and drug development. The derivatization of "an olefin" inside aromatic rings represents an ideal approach to access functionalized saturated heterocycles from abundant aromatic building blocks. Here, we… read more here.
Keywords: isoquinolines via; regioselective hat; via regioselective; semireduction quinolines ... See more keywords