Selective Construction of All-Carbon Quaternary Centers via Relay Catalysis of Indole C-H Functionalization/Allylic Alkylation.
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DOI: 10.1021/acs.orglett.2c03543
Abstract: Herein, a novel [Rh]2-catalyzed three-component reaction of readily accessible indoles, diazo compounds, and allylic compounds is developed via a relay carbene-induced C-H functionalization and allylic alkylation process, affording diverse C3-substituted indoles bearing all-carbon quaternary centers… read more here.
Keywords: carbon; functionalization allylic; carbon quaternary; via relay ... See more keywords