Cobalt-Catalyzed Dearomatization of Indoles via Transfer Hydrogenation To Afford Polycyclic Indolines.
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DOI: 10.1021/acs.orglett.1c00354
Abstract: A cobalt-catalyzed dearomatization of indoles via transfer hydrogenation with HBpin and H2O has been developed. This reaction offered a straightforward platform to access hexahydropyrido[1,2-a]indoles in high regio- and chemoselectivity. A preliminary reaction mechanism was proposed… read more here.
Keywords: catalyzed dearomatization; via transfer; transfer hydrogenation; cobalt catalyzed ... See more keywords