LAUSR

About LAUSR
Donate
Contact Us

Follow us:

You are not signed in:

Sign Up!


   Articles with "villiger oxidation" as a keyword



Dynamic Linkage Microregulation at Atomic Nodes in Heptazine‐Based Polymeric Networks for Enhanced Photocatalytic Baeyer‐Villiger Oxidation

Sign Up to like & get
recommendations! Published in 2025 at "Advanced Functional Materials"

DOI: 10.1002/adfm.202518990

Abstract: In pursuit of conventional harsh reaction conditions, production of industrially important precursor of poly(ɛ‐caprolactone) via Baeyer‐Villiger oxidation challenged its environmental viability. Thus, development of reliable, cost‐effective, and sustainable catalytic system always remains a key challenge. In this context, metal‐free… read more here.

Keywords: baeyer villiger; oxidation; polymeric networks; villiger oxidation ... See more keywords

Influence of Hydrophilicity on the Snβ‐Catalyzed Baeyer–Villiger Oxidation of Cyclohexanone with Aqueous Hydrogen Peroxide

Sign Up to like & get
recommendations! Published in 2017 at "ChemCatChem"

DOI: 10.1002/cctc.201600893

Abstract: Snβ zeolites are amongst the most effective heterogeneous catalysts for the Baeyer–Villiger (BV) oxidation of ketones with aqueous hydrogen peroxide (H2O2). The high selectivity is rooted in the activation of the carbonyl substrate through interaction… read more here.

Keywords: oxidation; baeyer villiger; hydrogen peroxide; aqueous hydrogen ... See more keywords

N‐Hydroxyphthalimide (NHPI) Promoted Aerobic Baeyer‐Villiger Oxidation in the Presence of Aldehydes

Sign Up to like & get
recommendations! Published in 2018 at "ChemCatChem"

DOI: 10.1002/cctc.201801165

Abstract: Metal‐free aerobic Baeyer‐Villiger (BV) oxidation of ketones to lactones or esters in the presence of aldehydes promoted by N‐hydroxyphthalimide (NHPI) has been developed. The reaction proceeded under mild conditions with excellent selectivity and high yields.… read more here.

Keywords: aerobic baeyer; oxidation; baeyer villiger; hydroxyphthalimide nhpi ... See more keywords

Free available chlorine initiated Baeyer-Villiger oxidation: A key mechanism for chloroform formation during aqueous chlorination of benzophenone UV filters.

Sign Up to like & get
recommendations! Published in 2020 at "Environmental pollution"

DOI: 10.1016/j.envpol.2020.115737

Abstract: Chloroform, a regulated disinfection by-product in water, is often generated during chlorination disinfection treatment. However, the formation of chloroform is heavily dependent on the molecular structures of precursors. Moreover, compounds containing ketone moiety are ubiquitous… read more here.

Keywords: baeyer villiger; chlorination; formation; villiger oxidation ... See more keywords

In Situ Synthesis of Iron-Based Porphyrin Metal-Organic Frameworks for the Baeyer-Villiger Oxidation Using Air as an Oxidant.

Sign Up to like & get
recommendations! Published in 2024 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.4c03337

Abstract: Iron-based porphyrin metal-organic frameworks (PMOFs) are a new type of material with good stability, catalytic activities, and reusability, which have broad application prospects. However, the synthesis of iron-based PMOFs with different metalloporphyrin units requires a… read more here.

Keywords: villiger oxidation; baeyer villiger; iron; synthesis iron ... See more keywords

Cu(ii)/SPDO complex catalyzed asymmetric Baeyer–Villiger oxidation of 2-arylcyclobutanones and its application for the total synthesis of eupomatilones 5 and 6

Sign Up to like & get
recommendations! Published in 2022 at "Chemical Science"

DOI: 10.1039/d2sc02079c

Abstract: A novel classical kinetic resolution of 2-aryl-substituted or 2,3-disubstituted cyclobutanones of Baeyer–Villiger oxidation catalyzed by a Cu(ii)/SPDO complex is reported for the first time, producing normal lactones in excellent enantioselectivities (up to 96% ee) and… read more here.

Keywords: baeyer villiger; spdo complex; villiger oxidation; catalyzed asymmetric ... See more keywords

Catalytic and Stoichiometric Baeyer–Villiger Oxidation Mediated by Nonheme Peroxo-Diiron(III), Acylperoxo, and Iodosylbenzene Iron(III) Intermediates

Sign Up to like & get
recommendations! Published in 2022 at "Molecules"

DOI: 10.3390/molecules27092814

Abstract: In this paper we describe a detailed mechanistic studies on the [FeII(PBO)2(CF3SO3)2] (1), [FeII(PBT)2(CF3SO3)2] (2), and [FeII(PBI)3](CF3SO3)2 (3)-catalyzed (PBO = 2-(2′-pyridyl)benzoxazole, PBT = 2-(2′-pyridyl)benzthiazole, PBI = 2-(2′-pyridyl)benzimidazole) Baeyer–Villiger oxidation of cycloketones by dioxygen with cooxidation… read more here.

Keywords: baeyer villiger; villiger oxidation; iii; diiron iii ... See more keywords