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Published in 2019 at "Chemistry of Heterocyclic Compounds"
DOI: 10.1007/s10593-019-02416-6
Abstract: A series of new derivatives of formylxanthenes have been synthesized via the reaction of substituted 1,3-benzoxazines with Vilsmeier–Haack reagent. It has been shown that 1,3-benzoxazines unsubstituted in the aromatic part and 6-bromo-1,3-benzoxazines are rearranged into…
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Keywords:
vilsmeier haack;
xanthene derivatives;
facile approach;
haack reagent ... See more keywords
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Published in 2019 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.11.030
Abstract: Abstract This research work is about the synthesis of pyranoquinolone-3carbaldehydes, heterocyclic compounds which were constructed by modifying Vilsmeier-Haack reaction. A leading approach towards green chemistry and successful methodology was devised during this research project for…
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Keywords:
haack reaction;
vilsmeier haack;
methodology;
synthesis ... See more keywords
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Published in 2020 at "Polycyclic Aromatic Compounds"
DOI: 10.1080/10406638.2018.1458739
Abstract: ABSTRACT The unexpected result for the formylation of N-ethylcarbazole under the Vilsmeier–Haack conditions (POCl3/DMF) led to the synthesis of novel methylene bridged bis-pyrrolo[3,2-c]carbazoles via Hemetsberger indole synthesis was reported. A plausible mechanism for the formation…
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Keywords:
pyrrolo carbazoles;
methylene bridged;
bridged bis;
vilsmeier haack ... See more keywords
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Published in 2020 at "Russian Journal of General Chemistry"
DOI: 10.1134/s1070363220040301
Abstract: Abstract Formylation of 6-methyl-2 S -substituted pyrimidin-4-ols under the conditions of the Vilsmeier–Haack reaction leads to the formation of nucleophilic substitution products of the hydroxyl group. The formation of the expected formylation products does not…
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Keywords:
methyl substituted;
substituted pyrimidin;
pyrimidin ols;
vilsmeier haack ... See more keywords