Cationic Terpolymerization of Vinyl Ethers, Oxetane, and Ketones via Concurrent Vinyl-Addition, Ring-Opening, and Carbonyl-Addition Mechanisms: Multiblock Polymer Synthesis and Mechanistic Investigation
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b01250
Abstract: Cationic terpolymerization of an alkyl vinyl ether (VE) with oxetane and methyl ethyl ketone (MEK) proceeded via concurrent vinyl-addition, ring-opening, and carbonyl-addition mechanisms. Highly selective crossover reactions occurred in a one-way cycle, resulting in the… read more here.
Keywords: addition; cationic terpolymerization; vinyl; via concurrent ... See more keywords
Highly Conductive Anion-Exchange Membranes Based on Cross-Linked Poly(norbornene): Vinyl Addition Polymerization
Sign Up to like & getrecommendations! Published in 2019 at "ACS Applied Energy Materials"
DOI: 10.1021/acsaem.8b02051
Abstract: Cross-linked (XL) anion-exchange membranes (AEMs) synthesized by vinyl addition polymerization of norbornene were prepared for use in anion-exchange membrane electrochemical devices, including fuel... read more here.
Keywords: vinyl addition; anion; anion exchange; cross linked ... See more keywords
Concurrent Cationic Vinyl-Addition and Coordination Ring-Opening Copolymerization via Orthogonal Propagation and Transient Merging at the Propagating Chain End
Sign Up to like & getrecommendations! Published in 2017 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.7b00095
Abstract: Controlled cationic vinyl-addition polymerization of an alkyl vinyl ether (VE) and ring-opening polymerization of e-caprolactone (CL) simultaneously proceeded using HfCl4/Hf(OBu)4 as a dual-role catalyst for both mechanisms, yielding a graft copolymer consisting of a poly(VE)… read more here.
Keywords: chain; ring opening; cationic vinyl; vinyl ... See more keywords
Sugar-Functional Vinyl Addition Poly(norbornene)–Photopatternable Poly(norbornenyl gluconamide) Compositions Developed with Water
Sign Up to like & getrecommendations! Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b00081
Abstract: The norbornenyl gluconamide (NBGA) monomer can be polymerized by a number of palladium catalysts to give water-soluble, vinyl addition poly(NBGA). Depending on the catalyst used, the reaction conditions, and the chain-transfer additives employed, high-molecular-weight polymers… read more here.
Keywords: addition poly; water; poly; vinyl addition ... See more keywords