Promiscuous Lipase-Catalyzed Markovnikov Addition of H-Phosphites to Vinyl Esters for the Synthesis of Cytotoxic α-Acyloxy Phosphonate Derivatives
Sign Up to like & getrecommendations! Published in 2022 at "Materials"
DOI: 10.3390/ma15051975
Abstract: An enzymatic route for phosphorous-carbon- bond formation is developed by discovering new promiscuous activity of lipase. This biocatalytic transformation of phosphorous-carbon- bond addition leads to biologically and pharmacologically relevant α-acyloxy phosphonates with methyl group in… read more here.
Keywords: phosphites vinyl; vinyl esters; lipase; markovnikov addition ... See more keywords
Synthesis of vinyl esters of aromatic carboxylic acids in the presence of Zn/SiOC, ZnO/SiOC, and Ni/SiOC catalytic systems
Sign Up to like & getrecommendations! Published in 2025 at "Turkish Journal of Chemistry"
DOI: 10.55730/1300-0527.3750
Abstract: In this work, various aromatic monocarboxylic and dicarboxylic acids were subjected for the first time to a vinylation reaction with acetylene under heterogeneous catalytic conditions using catalytic systems based on silicon oxycarbide supported on silicon… read more here.
Keywords: aromatic carboxylic; sioc; catalytic systems; acid ... See more keywords