Articles with "vinyl ether" as a keyword



Unraveling the Potential of Vinyl Ether as an Ethylene Surrogate in Heteroarene C─H Functionalization via the Spin‐Center Shift

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Published in 2024 at "Advanced Science"

DOI: 10.1002/advs.202309800

Abstract: Despite the simplicity and abundance of ethylene, its practical application presents significant hurdles due to its nature as a highly flammable gas. Herein, a strategic use of easily handled vinyl ether is reported as a… read more here.

Keywords: via spin; vinyl ether; ethylene; ethylene surrogate ... See more keywords
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Lewis-Base-Catalyzed Alkylation Reaction of 4-Hydroxycoumarins with Allenoates: Regioselective Synthesis of 2H-[3,2-c] Furocoumarins and 4-Hydroxycoumarin Vinyl Ether Derivatives

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Published in 2017 at "Asian Journal of Organic Chemistry"

DOI: 10.1002/ajoc.201600631

Abstract: A milder, more regioselective and practical approach to C3 or O-alkylation reaction of 4-hydroxycoumarins has been established. Both 2H-[3,2-c] furocoumarins and 4-hydroxycoumarin vinyl ether derivatives could be efficiently prepared by alkylating 4-hydroxycoumarins with electron-deficient allenoates… read more here.

Keywords: vinyl ether; furocoumarins hydroxycoumarin; reaction hydroxycoumarins; reaction ... See more keywords
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Synthesis of glucosamine vinyl ether derivative and its deuterated analog

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Published in 2020 at "Russian Chemical Bulletin"

DOI: 10.1007/s11172-020-2915-3

Abstract: The use of calcium carbide (in the presence of H2O) as a source of acetylene in the reaction with methyl 2-amino-4,6-O-benzylidene-2-deoxy-β-d-glucopyranoside under superbasic conditions (KF, KOH, DMSO, 130 °C, 3 h) led to the corresponding… read more here.

Keywords: glucosamine vinyl; deuterated analog; vinyl ether; synthesis glucosamine ... See more keywords

Atmospheric degradation of 2-chloroethyl vinyl ether, allyl ether and allyl ethyl ether: Kinetics with OH radicals and UV photochemistry.

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Published in 2017 at "Chemosphere"

DOI: 10.1016/j.chemosphere.2017.04.053

Abstract: Unsaturated ethers are oxygenated volatile organic compounds (OVOCs) emitted by anthropogenic sources. Potential removal processes in the troposphere are initiated by hydroxyl (OH) radicals and photochemistry. In this work, we report for the first time… read more here.

Keywords: ether allyl; chloroethyl vinyl; allyl ether; radicals photochemistry ... See more keywords

Bioadhesive poly(methyl vinyl ether-co-maleic anhydride)-TPGS copolymer modified PLGA/lipid hybrid nanoparticles for improving intestinal absorption of cabazitaxel.

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Published in 2021 at "International journal of pharmaceutics"

DOI: 10.1016/j.ijpharm.2021.121301

Abstract: A bioadhesive nanocarrier, PTNP, was constructed by utilizing a novel poly(methyl vinyl ether-co-maleic anhydride)- D-α-Tocopheryl polyethylene glycol succinate (PVMMA-TPGS) copolymer in the PLGA/lipid hybrid nanoparticles (PLGA NPs) for improving oral delivery of cabazitaxel (CTX). The… read more here.

Keywords: maleic anhydride; methyl vinyl; ether maleic; ctx ... See more keywords

Influence of vinyl ether intermediate over formation of Cβ=O and Cα=Cβ monomers during pyrolysis of lignin model dimers

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Published in 2019 at "Journal of Analytical and Applied Pyrolysis"

DOI: 10.1016/j.jaap.2018.11.009

Abstract: Abstract Radical chain reactions of a β-ether-type lignin model dimer, 1-(3,4-dimethoxyphenyl)-2-(2-methoxyphenoxy)-1-propanol, were reinvestigated at 350 °C in closed ampoule reactors under the influence of wood (Japanese cedar) pyrolysis. The formation of vinyl ether dimers and Cβ=O… read more here.

Keywords: dimer; phenolic dimer; formation; vinyl ether ... See more keywords

A biomimetic nano-hydroxyapatite/chitosan/poly(methyl vinyl ether-alt-maleic anhydride) composite with excellent biocompatibility

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Published in 2020 at "Materials Letters"

DOI: 10.1016/j.matlet.2019.127102

Abstract: Abstract Nano-hydroxyapatite/chitosan/poly(methyl vinyl ether-alt-maleic anhydride) (NHA/CS/P(MVE-alt-MA)) composite was formed through electrostatic interaction. The results of characterization indicated that the nano-hydroxyapatite (NHA) in the composites was uniformly distributed in the polymer matrices (chitosan/poly(methyl vinyl ether-alt-maleic anhydride)… read more here.

Keywords: methyl vinyl; chitosan poly; vinyl ether; poly methyl ... See more keywords
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Fluorescence enhancement and encapsulation of quantum dots via a novel crosslinked vinyl-ether liquid crystals/polymer composite film

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Published in 2020 at "Polymer"

DOI: 10.1016/j.polymer.2020.122834

Abstract: Abstract Fluorescence efficiency and stability of quantum dots (QDs) film, which are both key for optoelectronic device, are relatively difficult to be improved simultaneously. Herein, the facile synthesis of vinyl-ether terminated liquid crystals was reported.… read more here.

Keywords: fluorescence; vinyl ether; ether liquid; liquid crystals ... See more keywords

Synthesis of Various Poly(2-hydroxyethyl vinyl ether)-Stabilized Latex Particles via Surfactant-Free Emulsion Polymerization in Water

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Published in 2018 at "Macromolecules"

DOI: 10.1021/acs.macromol.7b02417

Abstract: Following the recent success of the controlled radical polymerization of hydroxy-functional vinyl ethers [Macromolecules 2016, 49, 1563; 2017, 50, 8346], we report a surfactant-free, batch emulsion polymerization stabilized by the poly(hydroxy-functional vinyl ether)s. A series… read more here.

Keywords: polymerization; surfactant free; emulsion polymerization; vinyl ether ... See more keywords

Liraglutide-Conjugated Poly(methyl vinyl ether-alt-maleic acid)-Coated Core–Shell Upconversion Nanoparticles for Theranostics of Diabetes

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Published in 2025 at "ACS Applied Materials & Interfaces"

DOI: 10.1021/acsami.5c11275

Abstract: In the diagnostics of diabetes, specific targeting of drugs (e.g., liraglutide) to insulin-deficient β-cells with their simultaneous noninvasive imaging is currently needed. In this report, liraglutide (LGL)-conjugated poly(methyl vinyl ether-alt-maleic acid) (PMVEMA)-coated core–shell NaYF4:Yb,Er,Fe@NaYF4:Nd upconversion… read more here.

Keywords: vinyl ether; methyl vinyl; pmvema; upconversion ... See more keywords

Poly(methyl vinyl ether-alt-maleic acid) and ethyl monoester as building polymers for drug-loadable electrospun nanofibers

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Published in 2017 at "Scientific Reports"

DOI: 10.1038/s41598-017-17542-4

Abstract: New biomaterials are sought for the development of bioengineered nanostructures. In the present study, electrospun nanofibers have been synthesized by using poly(methyl vinyl ether-alt-maleic acid) and poly(methyl vinyl ether-alt-maleic ethyl monoester) (PMVEMA-Ac and PMVEMA-ES, respectively)… read more here.

Keywords: methyl vinyl; vinyl ether; poly methyl; ether alt ... See more keywords