Robust Bulky [P,O] Neutral Nickel Catalysts for Copolymerization of Ethylene with Polar Vinyl Monomers
Sign Up to like & getrecommendations! Published in 2018 at "ACS Catalysis"
DOI: 10.1021/acscatal.8b01088
Abstract: Several nickel complexes bearing sterically bulky phosphino-phenolate ([P,O]) ligands were synthesized and explored as catalysts for olefin (co)polymerization. In the absence of an activator, the complexes showed very high catalytic activities (up to 107 g… read more here.
Keywords: nickel; nickel catalysts; polar vinyl; robust bulky ... See more keywords
Liquid Metal Nanoparticles as Initiators for Radical Polymerization of Vinyl Monomers
Sign Up to like & getrecommendations! Published in 2019 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.9b00783
Abstract: Sonication of gallium or gallium-based liquid metals in an aqueous solution of vinyl monomers leads to rapid free radical polymerization (FRP), without the need for conventional molecular initiators. Under ambient conditions, a passivating native oxide… read more here.
Keywords: liquid metal; metal nanoparticles; radical polymerization; vinyl monomers ... See more keywords
Effect of anethole on the copolymerization of vinyl monomers
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/d0py00833h
Abstract: Anethole, a monomer that can be extracted from bioresources, cannot homopolymerize. Its ability to copolymerize with other vinyl monomers depends on both steric hindrance and the electronic nature of the comonomer. Its copolymerization behaviour with… read more here.
Keywords: copolymerization vinyl; vinyl monomers; vinyl; anethole copolymerization ... See more keywords
Functionalization of Polylactide with Multiple Tetraphenyethane Inifer Groups to Form PLA Block Copolymers with Vinyl Monomers
Sign Up to like & getrecommendations! Published in 2022 at "International Journal of Molecular Sciences"
DOI: 10.3390/ijms24010019
Abstract: In the present contribution, a new strategy for preparing block copolymers of polylactide (PLA), a bio-derived polymer of increasing importance, is described. The method should lead to multiblock copolymers of lactide with vinyl monomers (VM),… read more here.
Keywords: polylactide multiple; functionalization polylactide; inifer; block copolymers ... See more keywords