Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles
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DOI: 10.1021/jacs.6b13029
Abstract: We report a highly enantioselective CuH-catalyzed Markovnikov hydrosilylation of vinylarenes and vinyl heterocycles. This method has a broad scope and enables both the synthesis of isolable silanes and the conversion of crude products to chiral… read more here.
Keywords: markovnikov hydrosilylation; hydrosilylation vinylarenes; vinyl heterocycles; catalyzed markovnikov ... See more keywords