Dihydroazulene-vinylheptafulvene based photoswitchable lewis pairs for tunable H2 activation
Sign Up to like & getrecommendations! Published in 2019 at "International Journal of Hydrogen Energy"
DOI: 10.1016/j.ijhydene.2019.03.251
Abstract: Abstract Photoswitchable catalysis involves alteration in the intrinsic catalytic properties of an active species through a reversible photochemical transformation. Herein, we report dihydroazulene-vinylheptafulvene (DHA-VHF) based photoswitchable frustrated Lewis pairs (FLPs) for reversible hydrogen activation. The… read more here.
Keywords: based photoswitchable; dihydroazulene vinylheptafulvene; vinylheptafulvene; lewis pairs ... See more keywords
Phototunable Absorption and Nonlinear Optical Properties of Thermally Stable Dihydroazulene–Vinylheptafulvene Photochrome Pair
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DOI: 10.1021/acsomega.2c04231
Abstract: The UV–vis absorption characteristics and nonlinear optical properties of a series of substituted dihydroazulene (DHA)/vinylheptafulvene (VHF) photoswitches are investigated by applying quantum calculations. Introduction of substituents at the seven-membered ring resulted in significant changes in… read more here.
Keywords: nonlinear optical; vinylheptafulvene; shift; absorption ... See more keywords