Competing C–H and C–F bond activation reactions of a fluorinated olefin at Rh: a fluorido vinylidene complex as an intermediate in an unprecedented dehydrofluorination step
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DOI: 10.1039/d1sc06713c
Abstract: The hydrofluoroolefin Z-1,3,3,3-tetrafluoropropene has been activated via an initial C–F bond activation and subsequent C–H bond activation using [Rh(H)(PEt3)3] (1) or via C–H bond activation at [Rh(CH3)(PEt3)3] (8). In both cases the formation of [Rh{(E)-CF… read more here.
Keywords: vinylidene complex; 320 320; bond activation; 600 600 ... See more keywords