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Iminium Substituent Directs Cyanide and Hydride Additions to Triiron Vinyliminium Complexes

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0 Published in 2023 at "New Journal of Chemistry"

DOI: 10.1039/d2nj05810c

Abstract: The reactivity of diiron bis-cyclopentadienyl cationic complexes containing a vinyliminium ligand coordinated to a diiron scaffold and decorated with a ferrocenyl group, [1a-g]CF3SO3, was investigated towards NBu4CN (in CH2Cl2) and... read more here.

Keywords: vinyliminium; cyanide hydride; substituent directs; hydride additions ... See more keywords

The beneficial effect of cyclohexyl substituent on the in vitro anticancer activity of diiron vinyliminium complexes.

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2 Published in 2023 at "Dalton transactions"

DOI: 10.1039/d3dt00186e

Abstract: Novel diiron vinyliminium complexes, [Fe2Cp2(CO)(μ-CO){μ-η1:η3-C(R3)CHCNMe(R2)}]CF3SO3 (2a-f; R2 = 4-C6H4OMe, Cy or Me; R3 = Cy, CH2Cy or 4-C6H4OMe; Cy = cyclohexyl, Cp = η5-C5H5), were synthesized by alkyne insertion reaction from the corresponding diiron aminocarbyne… read more here.

Keywords: vinyliminium; cyclohexyl; activity; vinyliminium complexes ... See more keywords