Vanadium(VIV)-Porphyrin-Based Metal-Organic Frameworks for Synergistic Bimetallic Activation of Inert C(sp3)-H Bonds.
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DOI: 10.1021/acsami.1c20420
Abstract: Activation and selective functionalization of inert C(sp3)-H bonds remain one of the most challenging tasks in current synthetic chemistry. Herein, by decorating vanadium(VIV)-porphyrin into metal-organic frameworks (MOFs) to stabilize the active tertbutyl peroxide radical, we… read more here.
Keywords: sp3 bonds; viv porphyrin; inert sp3; activation ... See more keywords