New Volatile Tantalum Imido Precursors with Carboxamide Ligands
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DOI: 10.1021/acsomega.1c03659
Abstract: A series of Ta(V) tBu-imido/N-alkoxy carboxamide complexes, TaCl2(NtBu)(pyridine)(edpa) (1), TaCl(NtBu)(edpa)2 (2), Ta(NtBu)(edpa)3 (3), TaCl2(NtBu)(pyridine)(mdpa) (4), and Ta(NtBu)(mdpa)3 (5), were successfully synthesized by metathesis reactions between Ta(NtBu)Cl3(py)2 and several equivalents of Na(edpa) (edpaH = N-ethoxy-2,2-dimethylpropanamide) and… read more here.
Keywords: imido; carboxamide ligands; spectroscopy; volatile tantalum ... See more keywords