Cationic Palladium(II) Complexes for Catalytic Wacker-Type Oxidation of Styrenes to Ketones using O2 as the Sole Oxidant
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700931
Abstract: A series of new palladium(II) complexes were prepared and studied for their ability to catalyze the Wacker-type oxidation of styrenes to their corresponding acetophenones using oxygen as the sole oxidant. Catalysts are active at room… read more here.
Keywords: sole oxidant; palladium complexes; wacker type; oxidation styrenes ... See more keywords
Enantioselective Aza-Wacker-Type Cyclization Promoted by Pd-SPRIX Catalyst.
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DOI: 10.1021/acs.orglett.8b02946
Abstract: An enantioselective aza-Wacker-type reaction was developed. When alkenyl sulfonamide substrates were treated with the Pd-SPRIX catalyst in the presence of oxone as an oxidant, the olefin was attacked intramolecularly by the nitrogen nucleophile to construct… read more here.
Keywords: aza wacker; wacker type; enantioselective aza; sprix catalyst ... See more keywords
Nickel-catalyzed remote and proximal Wacker-type oxidation
Sign Up to like & getrecommendations! Published in 2019 at "Communications Chemistry"
DOI: 10.1038/s42004-018-0107-y
Abstract: Wacker oxidation chemistry is widely applied to oxidation of olefins to carbonyls in the synthesis of pharmaceuticals, natural products, and commodity chemicals. However, in this chemistry efficient oxidation of internal olefins and highly selective oxidation… read more here.
Keywords: oxidation; wacker type; catalyzed remote; chemistry ... See more keywords