Amides as Weak Coordinating Groups in Proximal C–H Bond Activation
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DOI: 10.1002/ejoc.201700546
Abstract: Site selectivity is an inherent challenge in C–H functionalization reactions. The most intensively sought-after approaches have involved the employment of Lewis-basic coordinating groups to direct a metal to a proximal site, in the process generating… read more here.
Keywords: weak coordinating; coordinating groups; amides weak; groups proximal ... See more keywords
Weak Coordinating Character of Organosulfonates in Oriented Silica Films: An Efficient Approach for Immobilizing Cationic Metal-Transition Complexes
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DOI: 10.3390/molecules27175444
Abstract: Iron (II) tris(2,2′-bipyridine) complexes, [Fe(bpy)3]2+, have been synthesized and immobilized in organosulfonate-functionalized nanostructured silica thin films taking advantage of the stabilization of [Fe(H2O)6]2+ species by hydrogen bonds to the anionic sulfonate moieties grafted to the… read more here.
Keywords: character organosulfonates; oriented silica; coordinating character; weak coordinating ... See more keywords