Weakening of Carbide-Platinum Bonds as a Probe for Ligand Donor Strengths.
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DOI: 10.1021/acs.inorgchem.7b01956
Abstract: We report the observation of the weakening of the RuC-Pt single bond in (Cy3P)2Cl2Ru≡C-PtCl2-L (Ru≡C-Pt-L) complexes, leading to the incipient formation of the terminal ruthenium carbide complex, (Cy3P)2Cl2Ru≡C (RuC). In the solid state, elongation of… read more here.
Keywords: carbide platinum; carbide; weakening carbide; ruc ... See more keywords