Catalytic properties of chemical transformation within the confined pockets of Werner-type capsules
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DOI: 10.1016/j.ccr.2017.11.005
Abstract: Abstract The use of small molecules with defined cavities that catalyze unique chemical transformations to emulate enzyme sites have resulted in sustainable catalytic transformation with unprecedented selectivity that proceed under ambient conditions using benign solvents… read more here.
Keywords: werner type; within confined; catalytic properties; confined pockets ... See more keywords
Werner type clathrates involving guest benzoic acid and benzoate in discrete Mn(II) hosts: Experimental and theoretical studies
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DOI: 10.1016/j.poly.2018.11.068
Abstract: Abstract Two Werner type clathrates, viz. [Mn(phen)2Cl2]·bzH (2) and [Mn(phen)2Cl(H2O)]·4–NO2bz·3H2O (3) [phen = 1,10-phenanthroline, bzH = benzoic acid 4–NO2bz = 4-nitrobenzoate], have been synthesized from a complex precursor [Mn(phen)2Cl2] (1). The synthesized compounds have been characterized by X-ray crystal structure analysis,… read more here.
Keywords: werner type; benzoic acid; bzh; type clathrates ... See more keywords