Copper(I) Complexes of a Flexible Bis-phospholane Ligand: Route to Paddle-Wheel- and Box-Type Macrocycles.
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DOI: 10.1021/acs.inorgchem.7b01046
Abstract: Two bis-phospholane copper(I) metallamacrocycles were selectively synthesized starting from the same two building blocks, namely, ligand 1 and [Cu(NCCH3)4]BF4. Reaction conditions (ligand:metal (L:M) ratio and dilution) can be tuned to obtain either a paddle-wheel- (2,… read more here.
Keywords: paddle wheel; bis phospholane; copper; box type ... See more keywords