A New Family of Fe4Ln4 (Ln = DyIII, GdIII, YIII) Wheel type Complexes with Ferromagnetic Interaction, Magnetocaloric Effect and Zero-field SMM Behavior
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic Chemistry Frontiers"
DOI: 10.1039/d1qi00781e
Abstract: In this work, we report three isostructural Fe4Ln4 wheel type complexes with molecular formula [{Fe4(dea)4Dy4(deaH)8(µ2-OMe)4}(NO3)4]·4(H2O) (1), [{Fe4(dea)4Gd4(deaH)8(µ2-OMe)4}‧(NO3)4]·4(H2O)·4(MeOH) (2) and [{Fe4(dea)4Y4(deaH)8(µ2-OMe)4}(NO3)4]·4(H2O)·6(MeOH) (3), (where dea = diethanolamine). Detailed structural analysis disclose that... read more here.
Keywords: wheel type; fe4ln4; type complexes; dea ... See more keywords