Bis(α-hydroxycycloalkyl)phosphine Oxides Obtained from White Phosphorus via Phosphine Oxide H3 PO: Synthesis, Molecular Structure, Coordination Properties and Biological Activity.
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DOI: 10.1002/cplu.202000220
Abstract: Reaction of the electrochemically in situ from elemental white phosphorus generated phosphine oxide H3 PO in a single electrochemical cell, supplied with lead cathode and aluminium anode, with cyclic ketones (cyclopentanone and cyclohexanone) results in formation… read more here.
Keywords: phosphine oxide; white phosphorus; phosphine; bis ... See more keywords
Ionic liquids as beneficial medium for electrochemically induced transformation and functionalization of white phosphorus
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DOI: 10.1007/s11581-019-03069-3
Abstract: AbstractUnusual application of ionic liquids as the promoter for selective white phosphorus tetrahedron opening and reagent in the electrochemical reaction was described. New single-stage electrochemical synthesis of esters of phosphoric acids from white phosphorus in… read more here.
Keywords: white phosphorus; phosphorus; beneficial medium; liquids beneficial ... See more keywords
Electrolytic Synthesis of White Phosphorus Is Promoted in Oxide-Deficient Molten Salts
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DOI: 10.1021/acscentsci.2c01336
Abstract: Elemental white phosphorus (P4) is a key feedstock for the entire phosphorus-derived chemicals industry, spanning everything from herbicides to food additives. The electrochemical reduction of phosphate salts could enable the sustainable production of P4; however,… read more here.
Keywords: white phosphorus; phosphorus; electrolytic synthesis; phosphorus promoted ... See more keywords
Pentaphosphaferrocene-mediated synthesis of asymmetric organo-phosphines starting from white phosphorus
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DOI: 10.1038/s41467-021-26002-7
Abstract: The synthesis of phosphines is based on white phosphorus, which is usually converted to PCl3, to be afterwards substituted step by step in a non-atomic efficient manner. Herein, we describe an alternative efficient transition metal-mediated… read more here.
Keywords: synthesis asymmetric; pentaphosphaferrocene mediated; white phosphorus; phosphorus ... See more keywords
Hydrosilylation and hydrogermylation of white phosphorus
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DOI: 10.1039/d5qi00869g
Abstract: The development of efficient, direct strategies for the transformation of white phosphorus (P4) into useful monophosphorus compounds, as alternatives to the current wasteful and hazardous indirect processes, remains a significant... read more here.
Keywords: chemistry; white phosphorus; hydrosilylation hydrogermylation; phosphorus ... See more keywords
Adduct-catalyzed tandem electro-thermal synthesis of organophosphorus (III) compounds from white phosphorus
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DOI: 10.1093/nsr/nwaf008
Abstract: ABSTRACT Electrooxidation strategies for synthesizing readily oxidizable products face notable challenges, especially when the oxidation potential of the products is lower than that of the reactants or when high current densities are necessary. The electrooxidation… read more here.
Keywords: tandem electro; white phosphorus; adduct; electro thermal ... See more keywords
Hydrogenation reaction pathways in chemistry of white phosphorus
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DOI: 10.1515/pac-2018-1007
Abstract: Abstract Approaches for preparation of P–H bond containing derivatives directly from white phosphorus are summarized in this microreview. Transfer hydrogenation of P4 involving the activation and reaction of white phosphorus in the coordination sphere of… read more here.
Keywords: chemistry; hydrogenation reaction; white phosphorus; phosphorus ... See more keywords