Reactivity of a Dithiocarbamate-Ligated [WVI≡S] Complex with Hydride Donors: Toward a Synthetic Mimic of Formate Dehydrogenase.
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DOI: 10.1021/acs.inorgchem.3c00086
Abstract: Formate dehydrogenase (FDH) enzymes catalyze redox interconversion of CO2 and HCO2-, with a key mechanistic step being the transfer of H- from HCO2- to an oxidized active site featuring a [MVI≡S] group in a sulfur-rich… read more here.
Keywords: wvi complex; formate dehydrogenase; donors toward; hydride ... See more keywords