An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity.
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DOI: 10.1021/jacs.8b11605
Abstract: The first zerovalent germanium complex ("germylone") 3, [SiII(Xant)SiII]Ge0, stabilized by a chelating bis(N-heterocyclic silylene)xanthene donor ligand 1 was successfully synthesized via the dechlorination of the corresponding {[SiII(Xant)SiII]GeCl}+Cl- complex 2 with KC8; it was structurally and… read more here.
Keywords: xant siii; siii; germylone; silylene ... See more keywords