Phosphonium Ylides vs Iminophosphoranes: The Role of the Coordinating Ylidic Atom in cis-[Phosphine-Ylide Rh(CO)2] Complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04151
Abstract: The coordinating properties of two families of ylides, namely, phosphonium ylides and iminophosphoranes, differently substituted at the ylidic center (CH2- vs NiPr-), have been investigated in structurally related cationic phosphine-ylide Rh(CO)2 complexes obtained from readily… read more here.
Keywords: phosphine; ylides iminophosphoranes; phosphine ylide; ylide ... See more keywords
Isolation and characterisation of a stable 2-azaphenalenyl azomethine ylide
Sign Up to like & getrecommendations! Published in 2019 at "Communications Chemistry"
DOI: 10.1038/s42004-019-0236-y
Abstract: Although azomethine ylides have been fully exploited as versatile reactive intermediates in dipolar cycloaddition reactions to construct a variety of heterocyclic compounds involving a nitrogen atom, little is known about their structural and electronic properties.… read more here.
Keywords: ylide; phenyl butyl; stable azaphenalenyl; azomethine ylide ... See more keywords