Synthesis of Axially Chiral 1,2,3-Triazol-5-ylidene–Au(I) Complex and Its Application in Enantioselective [2 + 2] Cycloaddition of Alleneamides with Alkenes
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DOI: 10.1021/acs.organomet.8b00524
Abstract: A series of axially chiral bis-1,2,3-triazol-5-ylidene Au(I) complexes (R)-8a–g and one mono-1,2,3-triazol-5-ylidene Au(I) complex (R)-9a were prepared from commercially available (R)-binaphthyl-2,2-diamine (BINAM) compound, in which, transmetalation of bis(MIC)-bis[Ag(I)] intermediates to the corresponding Au(I) complexes were… read more here.
Keywords: triazol ylidene; ylidene complex; chiral bis; ylidene ... See more keywords