Ylidenenorbornadiene Carboxylates: Experimental Kinetic Analysis of a Nucleophile-Induced Fragmentation Reaction.
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DOI: 10.1021/acs.orglett.2c00630
Abstract: Ylidenenorbornadienes (YNDs), prepared by [4 + 2] cycloadditions between fulvenes and acetylene carboxylates, react with beta-mercaptoethanol to yield a mixture of four diastereomers. These four diastereomers fragment via a retro-[4 + 2] cycloaddition at differing… read more here.
Keywords: fragmentation; ylidenenorbornadiene carboxylates; experimental kinetic; analysis nucleophile ... See more keywords