Rh(III)-Catalyzed Cascade Reactions of Sulfoxonium Ylides with α-Diazocarbonyl Compounds: An Access to Highly Functionalized Naphthalenones.
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DOI: 10.1021/acs.orglett.9b00340
Abstract: An unprecedented cascade reaction of benzoyl sulfoxonium ylides with α-diazocarbonyl compounds leading to the formation of highly functionalized naphthalenones containing a β-ketosulfoxonium ylide moiety is presented. Promisingly, the naphthalenone derivative thus obtained was found to… read more here.
Keywords: iii catalyzed; sulfoxonium ylides; diazocarbonyl compounds; ylides diazocarbonyl ... See more keywords