Articles with "zerovalent" as a keyword



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Mitigating effect of nano-zerovalent iron, iron sulfate and EDTA against oxidative stress induced by chromium in Helianthus annuus L.

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Published in 2018 at "Acta Physiologiae Plantarum"

DOI: 10.1007/s11738-018-2647-2

Abstract: Due to its wide industrial application, chromium (Cr) is known to be a critical environmental pollutant. Contamination of water and agricultural soil by Cr inhibits crop productivity and their physiological and biochemical processes. The objective… read more here.

Keywords: iron sulfate; zerovalent; fe0 nanoparticles; iron ... See more keywords
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Seeking Redox Activity in a Tetrazinyl Pincer Ligand: Installing Zerovalent Cr and Mo.

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Published in 2018 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.8b01761

Abstract: Reaction of the readily reduced pincer ligand bis-tetrazinylpyridine, btzp, with the zerovalent metal source M(CO)3(MeCN)3 yields M(btzp)2 for M = Cr, Mo. These diamagnetic molecules show intrapincer bond lengths consistent with major charge transfer from… read more here.

Keywords: pincer; metal; zerovalent; seeking redox ... See more keywords
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Reactivity Enhancement of a Zerovalent Diboron Compound by Desymmetrization.

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Published in 2018 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.8b06930

Abstract: The desymmetrization of the cyclic (alkyl)(amino)carbene-supported diboracumulene B2(cAACMe)2 (cAACMe = 1-(2,6-diisopropylphenyl)-3,3,5,5-tetramethylpyrrolidin-2-ylidene) by monoadduct formation with IMeMe (1,3-dimethylimidazol-2-ylidene) yields the zerovalent sp-sp2 diboron compound B2(cAACMe)2(IMeMe), which provides a versatile platform for the synthesis of novel symmetrical… read more here.

Keywords: imeme; diboron; diboron compound; zerovalent ... See more keywords
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Environmental water remediation using covalently functionalized zerovalent iron nanocomposites with 2-pyridinecarboxaldehyde via 3-aminopropyltrimethoxysilane and ethylenediamine

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Published in 2019 at "Separation Science and Technology"

DOI: 10.1080/01496395.2018.1529045

Abstract: ABSTRACT The adsorption technology involving nano zerovalent iron (NZVI) has been widely employed to remediate polluted water based on a number of economic aspects. However, this technology is facing a high challenge in the removal… read more here.

Keywords: zerovalent iron; zerovalent; nzvi nh2; water ... See more keywords