Facile synthesis of a hexanuclear zinc-acetato-trimethylsilylphosphinidene cluster: a single-source precursor to Zn3P2 nanoparticles.
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DOI: 10.1039/c9cc04879k
Abstract: The selective synthesis of the zinc-acetato-phosphinidene cluster [Zn6(μ3-PSiMe3)4(OAc)4(NC5H5)5] 1 is presented. The cluster serves as a stable, single-source precursor to yield soluble zinc phosphide nanoparticles via P-Si bond activation and AcOSiMe3 elimination when heated in… read more here.
Keywords: single source; zinc; zinc acetato; source precursor ... See more keywords